Wall jump
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The faster characters in SSBM- namely, Mario, Samus, Fox, Falco, Pichu, Young Link, and Captain Falcon- have something called Wall jumps.
To Wall jump, simply jump at a wall and hit away from it once you hit it. You must hit the wall before reaching the peak of your jump, though. If successful, you'll perform a jumping animation and gain an extra jump (and even a bit of invincibility at the start of it to boot!).
